You can try this
Add a person or profile
On your computer, open Chrome.
At the top-right, click the button with your name or People .
Click Manage people.
Click Add person.
Choose a name and a photo.
Click Save A new window will open and ask you to sign in.
(Optional) Sign in to Chrome with a Google Account for the new profile. Their bookmarks, history, passwords and other settings will sync automatically.