Yes, wind on leaders for big game fishing off shore this is how it's done.
However they run the mono or flouro up to 3' inside the hollow core.
The also rough up the surface of the leader with some very fine sand paper every few inches so it is gripped better.
Finally they use waxed thread to serve the joint between the braid and leader.
This keeps the braid from unraveling.
As for using hollow core for fresh water fishing, I don't think it's worth the extra cost and effort.
Especially with hollow core being several times more expensive than non-hollow core.
Best to just use an FG knot to connect your braid to heavy leader.